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Sunshine is making Deepwater Horizon oil stick around

Author: Laurel Hamers / Source: Science News

oil spill
JUST ADD SUNLIGHT Oil swirls at the water’s surface after the 2010 Deepwater Horizon oil spill. Sunlight transformed the oil molecules on the surface into new molecules that are still sticking around.

Sunlight shapes oil spills’ long-term legacies.

In the days and weeks after the 2010 Deepwater Horizon oil spill in the Gulf of Mexico, sunlight hit the oil slicks on the surface of the water.

That triggered chemical reactions that added oxygen to oil molecules that once were just chains of carbon and hydrogen atoms. These oxygenated hydrocarbons are still sticking around eight years later with little evidence of degradation, researchers report May 29 in Environmental Science and Technology.

Chemist Christopher Reddy of Woods Hole Oceanographic Institution in Massachusetts and colleagues analyzed the oily soup of molecules floating in the Gulf post-disaster. (The Deepwater Horizon spill was the largest marine oil spill in U.S. history, leaking more than 3 million barrels.) While investigating how the leaked hydrocarbons broke down over time, the team got a surprise: More than half of the degrading oil by-products found in oil slicks from the spill were these oxygenated hydrocarbons, the researchers reported in 2012. The by-products had gone relatively unnoticed after previous oil spills, and so were mostly unstudied in that context.

Now the team has evidence that these oxygenated hydrocarbons aren’t just a major by-product of the Deepwater…

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