California’s crops are creating some noxious air.
The Golden State is at the vanguard in the United States in reducing auto emissions of nitrogen oxide gases, which help produce toxic smog and acid rain. But the NOx pollution problem isn’t limited to auto exhaust. California’s vast agricultural lands — particularly soils heavily treated with nitrogen fertilizers — are now responsible for as much as 51 percent of total NOx emissions across the state, researchers report January 31 in Science Advances.
The catchall term “NOx gases” generally refers to two pollution-promoting gases: nitric oxide, or NO, and nitrogen dioxide, or NO2. Those gases react with incoming sunlight to produce ozone in the troposphere, the lowest layer of the atmosphere. At high levels, tropospheric ozone can cause respiratory problems from asthma to emphysema.
Between 2005 and 2008, regulations issued by the California Air Resources Board on transportation exhaust reduced NOx levels in cities such as Los Angeles, San Francisco and Sacramento by 9 percent per year. However, the U.S. Environmental Protection Agency has increasingly recognized nitrogen fertilizer use as a significant source of NOx gases to the atmosphere.
NOx gases are produced in oxygen-poor soils when microbes break apart nitrogen compounds in the fertilizer, a process called denitrification. The release of those gases from fertilized soils increases at high temperatures due to increased microbial activity, says Darrel Jenerette, an ecologist at…
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